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WPI/Class I Wastewater/Formula Sheet

WPI Class I Wastewater Treatment

Formula & Reference Sheet — BC (EOCP) · AB (AWWOA) · SK (SAHO) · MB (MWWA)

Flow & Hydraulics

Flow Rate

Q = A × V
QFlow rate (m³/s or m³/d)
ACross-sectional area (m²)
VVelocity (m/s)
Example:A = 0.5 m², V = 0.3 m/s → Q = 0.15 m³/s
1 m³/s = 86,400 m³/d

Hydraulic Retention Time (HRT)

HRT = V ÷ Q
HRTHydraulic retention time (hours or days)
VTank volume (m³)
QFlow rate (m³/d)
Example:V = 2000 m³, Q = 5000 m³/d → HRT = 0.4 d = 9.6 h

Pump Head

TDH = Static Head + Friction Head + Minor Losses
TDHTotal dynamic head (m)
Static HeadElevation difference (m)
Friction HeadHead loss due to pipe friction (m)
Use Hazen-Williams or Darcy-Weisbach for friction head calculations.

Pump Power

P = (Q × ρ × g × TDH) ÷ η
PPower (W or kW)
QFlow rate (m³/s)
ρDensity of water (1000 kg/m³)
gGravitational acceleration (9.81 m/s²)
TDHTotal dynamic head (m)
ηPump efficiency (decimal)
Example:Q = 0.05 m³/s, TDH = 20 m, η = 0.75 → P = 13.1 kW

Manning's Equation (Gravity Sewers)

V = (1/n) × R^(2/3) × S^(1/2)
VFlow velocity (m/s)
nManning's roughness coefficient (0.013 for concrete)
RHydraulic radius (m) = Area / Wetted Perimeter
SSlope of the hydraulic grade line (m/m)
Minimum velocity for self-cleaning: 0.6 m/s (2 fps) at design flow.

Primary Treatment

Surface Overflow Rate (SOR)

SOR = Q ÷ A
SORSurface overflow rate (m³/m²·d)
QFlow rate (m³/d)
ASurface area of clarifier (m²)
Example:Q = 5000 m³/d, A = 400 m² → SOR = 12.5 m³/m²·d
Typical primary clarifier SOR: 24–48 m³/m²·d

Weir Overflow Rate (WOR)

WOR = Q ÷ L
WORWeir overflow rate (m³/m·d)
QFlow rate (m³/d)
LTotal weir length (m)
Typical WOR: < 250 m³/m·d for primary clarifiers

BOD Removal Efficiency

E = (BOD_in − BOD_out) ÷ BOD_in × 100%
ERemoval efficiency (%)
BOD_inInfluent BOD (mg/L)
BOD_outEffluent BOD (mg/L)
Example:BOD_in = 250 mg/L, BOD_out = 20 mg/L → E = 92%

Secondary Treatment (Activated Sludge)

Food-to-Microorganism Ratio (F/M)

F/M = (Q × BOD) ÷ (V × MLVSS)
F/MFood-to-microorganism ratio (kg BOD/kg MLVSS·d)
QFlow rate (m³/d)
BODInfluent BOD (mg/L or kg/m³)
VAeration tank volume (m³)
MLVSSMixed liquor volatile suspended solids (mg/L)
Example:Q = 5000 m³/d, BOD = 200 mg/L, V = 2000 m³, MLVSS = 2500 mg/L → F/M = 0.2 kg/kg·d
Typical F/M: 0.05–0.15 for extended aeration; 0.2–0.6 for conventional AS

Sludge Retention Time (SRT / SludgeAge)

SRT = (V × MLSS) ÷ (Q_w × SS_w)
SRTSludge retention time (days)
VAeration tank volume (m³)
MLSSMixed liquor suspended solids (mg/L)
Q_wWaste activated sludge flow rate (m³/d)
SS_wWAS suspended solids concentration (mg/L)
Example:V = 2000 m³, MLSS = 3000 mg/L, Q_w = 200 m³/d, SS_w = 8000 mg/L → SRT = 3.75 d
Nitrification requires SRT > 10 days at 15°C

Sludge Volume Index (SVI)

SVI = (SV₃₀ × 1000) ÷ MLSS
SVISludge volume index (mL/g)
SV₃₀Settled sludge volume after 30 min (mL/L)
MLSSMixed liquor suspended solids (mg/L)
Example:SV₃₀ = 250 mL/L, MLSS = 2500 mg/L → SVI = 100 mL/g
Good settling: SVI < 120 mL/g. Bulking: SVI > 200 mL/g

Return Activated Sludge (RAS) Rate

RAS% = SVI × MLSS ÷ (1000 − SVI × MLSS/1000) × 100
RAS%Return sludge ratio (% of influent flow)
SVISludge volume index (mL/g)
MLSSTarget MLSS (mg/L)
Simplified: RAS% ≈ MLSS / (RAS SS − MLSS) × 100. Typical RAS: 25–100% of Q.

Oxygen Demand (Theoretical)

O₂ = Q × (BOD_in − BOD_out) × 1.42 × (ΔX/ΔT)
O₂Oxygen required (kg/d)
QFlow rate (m³/d)
BODBOD concentration (mg/L = g/m³)
1.42O₂ equivalent of cell mass (kg O₂/kg VSS)
Simplified: O₂ demand ≈ 1.0–1.5 kg O₂ per kg BOD removed

Disinfection

Chlorine Dose

Dose = Demand + Residual
DoseChlorine added (mg/L)
DemandChlorine consumed by wastewater (mg/L)
ResidualChlorine remaining after contact time (mg/L)
Example:Demand = 6 mg/L, Residual = 2 mg/L → Dose = 8 mg/L

CT Value

CT = C × T
CTDisinfection CT value (mg·min/L)
CDisinfectant concentration (mg/L)
TContact time (minutes)
Example:C = 2 mg/L, T = 30 min → CT = 60 mg·min/L
Required CT for 4-log Giardia inactivation at 15°C: ~170 mg·min/L for free chlorine

Chlorine Feed Rate

Feed Rate = Q × Dose ÷ 1000
Feed RateChlorine feed rate (kg/d)
QFlow rate (m³/d)
DoseChlorine dose (mg/L = g/m³)
Example:Q = 5000 m³/d, Dose = 8 mg/L → Feed Rate = 40 kg/d

UV Dose

UV Dose = Irradiance × Exposure Time
UV DoseUV dose (mJ/cm²)
IrradianceUV intensity (mW/cm²)
Exposure TimeContact time (seconds)
Minimum UV dose for 4-log virus inactivation: 186 mJ/cm²

Solids Handling

Sludge Production

P = Q × (TSS_in − TSS_out) ÷ 1000
PSludge production (kg/d)
QFlow rate (m³/d)
TSS_inInfluent TSS (mg/L)
TSS_outEffluent TSS (mg/L)
Example:Q = 5000 m³/d, TSS_in = 250 mg/L, TSS_out = 20 mg/L → P = 1150 kg/d

Sludge Volume

V_sludge = P ÷ (ρ × %solids)
V_sludgeSludge volume (m³/d)
PSludge mass (kg/d)
ρSludge density (~1000 kg/m³ for liquid sludge)
%solidsSolids content (decimal)
Example:P = 1000 kg/d, %solids = 0.02 (2%) → V = 50 m³/d

Volatile Solids Reduction

VSR = (VS_in − VS_out) ÷ VS_in × 100%
VSRVolatile solids reduction (%)
VS_inVolatile solids fed to digester (kg/d)
VS_outVolatile solids leaving digester (kg/d)
Target VSR for anaerobic digestion: ≥ 38% (Class B biosolids requirement)

Digester Loading Rate

Loading = VS_fed ÷ V_digester
LoadingVolatile solids loading rate (kg VS/m³·d)
VS_fedVolatile solids fed (kg/d)
V_digesterDigester volume (m³)
Typical mesophilic digester loading: 1.6–4.8 kg VS/m³·d

Nutrient Removal

Nitrification Oxygen Demand

O₂_nitrification = 4.57 × ΔNH₃
O₂_nitrificationOxygen required for nitrification (mg/L)
4.57Stoichiometric O₂ demand per mg NH₃-N oxidized
ΔNH₃Ammonia removed (mg/L as N)
Example:ΔNH₃ = 30 mg/L → O₂ = 137 mg/L

Denitrification Alkalinity Recovery

Alkalinity recovered = 3.57 × ΔNO₃
Alkalinity recoveredAlkalinity produced (mg/L as CaCO₃)
3.57Alkalinity recovered per mg NO₃-N denitrified
ΔNO₃Nitrate removed (mg/L as N)

Phosphorus Removal — Alum Dose

Alum dose ≈ 9.6 × P_removed
Alum doseAlum required (mg/L as Al₂(SO₄)₃)
P_removedPhosphorus to be removed (mg/L as P)
Molar ratio Al:P ≈ 1.5–2.0 for reliable removal to < 1 mg/L

Phosphorus Removal — Ferric Chloride Dose

FeCl₃ dose ≈ 5.2 × P_removed
FeCl₃ doseFerric chloride required (mg/L)
P_removedPhosphorus to be removed (mg/L as P)
Molar ratio Fe:P ≈ 1.5–2.0 for reliable removal

Laboratory Calculations

BOD Calculation

BOD = (DO_initial − DO_final) × Dilution Factor
BODBiochemical oxygen demand (mg/L)
DO_initialInitial dissolved oxygen (mg/L)
DO_finalFinal dissolved oxygen after 5 days (mg/L)
Dilution FactorSample volume / Total volume
Example:DO_i = 8.5, DO_f = 3.5, DF = 10 → BOD = (8.5−3.5) × 10 = 50 mg/L

TSS Calculation

TSS = (W_filter+residue − W_filter) ÷ V_sample × 10⁶
TSSTotal suspended solids (mg/L)
WWeight of filter + residue after drying (g)
V_sampleVolume of sample filtered (mL)
Example:W_residue = 0.025 g, V = 500 mL → TSS = 50 mg/L

Dilution Factor

DF = V_total ÷ V_sample
DFDilution factor (dimensionless)
V_totalTotal volume of diluted sample (mL)
V_sampleVolume of original sample (mL)
Example:1 mL sample in 300 mL total → DF = 300

Percent Solids

%TS = (Dry weight ÷ Wet weight) × 100
%TSPercent total solids (%)
Dry weightWeight after drying at 105°C (g)
Wet weightWeight of wet sample (g)
Example:Dry = 25 g, Wet = 1000 g → %TS = 2.5%

Quick Reference — Typical Operating Ranges

ParameterTypical RangeUnitsNotes
Primary clarifier SOR24–48m³/m²·dAverage flow conditions
Secondary clarifier SOR16–32m³/m²·dAverage flow conditions
Aeration tank HRT4–8hoursConventional activated sludge
MLSS (conventional AS)1500–3000mg/L
MLSS (extended aeration)3000–6000mg/L
SRT (nitrification)> 10daysAt 15°C
SVI (good settling)< 120mL/g
SVI (bulking)> 200mL/g
F/M (conventional AS)0.2–0.6kg BOD/kg MLVSS·d
F/M (extended aeration)0.05–0.15kg BOD/kg MLVSS·d
RAS rate25–100% of Q
DO in aeration tank1.5–3.0mg/L
Digester SRT (mesophilic)15–30days
VS reduction (digestion)> 38%Class B requirement
Chlorine residual (effluent)0.5–1.0mg/LAfter 30-min contact

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